Mehta, Goverdhan ; Nandakumar, Jayakrishnan (2002) Novel tandem ring-opening/ring-closing metathesis reactions of functionalized cyclohexenoids derived from (-)-α-pinene Tetrahedron Letters, 43 (4). pp. 699-702. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(01)02223-7
Abstract
The cyclohexenone (+)-2, readily obtained from (-)-α -pinene 1 was elaborated to (+)-3 in an attempt to construct the AB rings of taxoids employing the ring-closure metathesis (RCM) reaction as the key step. In the event, a novel ring-opening/ring-closing metathesis reaction was encountered in the relatively strain free cyclohexenyl ring of (+)-3.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 29081 |
Deposited On: | 18 Dec 2010 05:38 |
Last Modified: | 17 May 2016 12:03 |
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