Rao, Chebrolu P. ; Sreedhara, A. (1999) Oxo-metal complexes of alkoxo rich ligands and reactivity of vanadium complexes Proceedings of the Indian Academy of Sciences - Chemical Sciences, 111 (3). pp. 479-487. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/111/6/479-4...
Related URL: http://dx.doi.org/10.1007/BF02870845
Abstract
Oxo-metal centers, such as, VO3+, cis-VO+2 , cis-MoO22+ andtrans-UO22+ exhibited different coordination geometries and charge types to result in totally nine different types of structures, all of which were characterized by single crystal X-ray diffraction. Aqueous stability, reactivity towards acid, H2O2 and bromide of vanadium complexes are studied using absorption and 51V NMR spectra. Catalytic nature of the bromination reaction by vanadium complexes has also been addressed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Vanadium Complexes; NMR Spectra; Catalytic Nature; Bromination Reaction |
| ID Code: | 79167 |
| Deposited On: | 24 Jan 2012 15:36 |
| Last Modified: | 18 May 2016 21:38 |
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