Chaudhuri, Mihir K. ; Ghosh, Soumitra K. ; Hiese, Zavei (1984) Synthesis of tetrafluoronickelate(II) and tetrafluorozincate(II) complexes from aqueous media: a novel route to fluorometalates Journal of the Chemical Society, Dalton Transactions (8). pp. 1763-1764. ISSN 0300-9246
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Official URL: http://www.rsc.org/publishing/journals/DT/article....
Related URL: http://dx.doi.org/10.1039/DT9840001763
Abstract
The complexes A2[NiF4](A = NH4+, K+, or Rb+) and A2[ZnF4](A = NH4+, K+, Rb+, or Cs+) have been synthesised, from the corresponding metal acetylacetonates (acac) with 40% HF and AF, in very high yields. The new method also allows the preparation of [VOF5]2-, [MnF5]2-, and [CrF5(H2O)]2- from [VO(acac)2], [Mn(acac)3], and [Cr(acac)3] respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 23550 |
| Deposited On: | 25 Nov 2010 13:09 |
| Last Modified: | 17 May 2016 07:21 |
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