Ghatak, Tapas ; Sarkar, Mithun ; Dinda, Shrabani ; Dutta, Indranil ; Rahaman, S. M. Wahidur ; Bera, Jitendra K. (2015) Olefin oxygenation by water on an iridium center Journal of the American Chemical Society, 137 (19). pp. 6168-6171. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jacs.5b03055?j...
Related URL: http://dx.doi.org/10.1021/jacs.5b03055
Abstract
Oxygenation of 1,5-cyclooctadiene (COD) is achieved on an iridium center using water as a reagent. A hydrogen-bonding interaction with an unbound nitrogen atom of the naphthyridine-based ligand architecture promotes nucleophilic attack of water to the metal-bound COD. Irida-oxetane and oxo-irida-allyl compounds are isolated, products which are normally accessed from reactions with H2O2 or O2. DFT studies support a ligand-assisted water activation mechanism.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 99851 |
| Deposited On: | 27 Nov 2016 13:29 |
| Last Modified: | 27 Nov 2016 13:29 |
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