Saha, Sayantani ; Daw, Prosenjit ; Bera, Jitendra K. (2015) Oxidative route to abnormal NHC compounds from singly bonded [M–M] (M = Ru, Rh, Pd) precursors Organometallics, 34 (23). pp. 5509-5512. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.organomet....
Related URL: http://dx.doi.org/10.1021/acs.organomet.5b00872
Abstract
A new base-free entry to metal-aNHC compounds from metal-metal bonded bimetallic precursors and imidazolium salts is reported. Regioselective metalation proceeds via C–I oxidative addition of an annulated imidazo[1,2-a][1,8]naphthyridine system to [RuI–RuI], [RhII–RhII], and [PdI–PdI] single bonds, affording C5-bound (abnormal) RuII–, RhIII–, and PdII–NHC compounds, respectively, at room temperature and in high yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 99808 |
| Deposited On: | 27 Nov 2016 13:29 |
| Last Modified: | 27 Nov 2016 13:29 |
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