Haldar, Debasish ; Banerjee, Arijit ; Drew, Michael G. B. ; Das, Apurba Kumar ; Banerjee, Arindam (2003) First crystallographic signature of an acyclic peptide nanorod: molecular mechanism of nanorod formation by a self-assembled tetrapeptide Chemical Communications (12). pp. 1406-1407. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2003...
Related URL: http://dx.doi.org/10.1039/B302472P
Abstract
A terminally protected acyclic tetrapeptide Boc-Aib-Val-Aib-β-Ala-OMe 1 (Aib: α-aminoisobutyric acid, β-Ala: β-Alanine) self-assembles into a continuous hydrogen-bonded supramolecular helix with an average diameter of 10Å (1nm) starting from a double bend molecular conformation in crystals and further self-assembly of this supramolecular architecture leads to the formation of polydisperse nanorods of diameters 10–40 nm.
Item Type: | Article |
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Source: | Copyright of this article belongs to Royal Society of Chemistry. |
ID Code: | 99521 |
Deposited On: | 04 Nov 2016 12:28 |
Last Modified: | 04 Nov 2016 12:28 |
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