Mohanty, Subhendu K. ; Thirunavukarasu, Shyamala ; Baskaran, Sundarababu ; Mishra, Ashok K. (2004) Self-association of protected Newkome-type second-generation dendrimers at nanomolar level concentrations in aqueous solution Macromolecules, 37 (14). pp. 5364-5369. ISSN 0024-9297
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ma0498215
Related URL: http://dx.doi.org/10.1021/ma0498215
Abstract
Protected Newkome-type second-generation dendrimers (based on Lin's amine) were synthesized with a pyrene moiety attached to the core. The photophysical property in aqueous solution of the protected dendrimers shows self-association behavior in water. Pyrene excimer emission at 475 nm is observed in water even at very low concentrations of protected dendrimer (ca. 5 × 10-8 M). This emission band is absent in other solvents even up to a concentration of 10-5 M. The corresponding unprotected dendrimer does not show the pyrene excimer fluorescence. The amide of pyrene butyric acid with tert-butylamine shows the formation of excimer, albeit with very low intensity. Quenching studies on the dendrimer with hydrophilic quencher iodide anion (I-) reveal that there is significant quenching of fluorescence intensity in the case of N-tert-butyl-4-pyren-1-ylbutyramide as compared to that of the pyrene-attached second-generation protected dendrimer. This shows that the pyrene moiety in the case of the protected dendrimer is significantly shielded from the surrounding.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 98557 |
Deposited On: | 19 Sep 2014 11:28 |
Last Modified: | 19 Sep 2014 11:28 |
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