Baskaran, Sundarababu ; Balakumar, Vijayakrishnan ; Aravind, Appu (2004) A highly regio- and chemoselective reductive cleavage of benzylidene acetals with EtAlCl2-Et3SiH Synlett (4). pp. 647-650. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/products/ejournals/...
Related URL: http://dx.doi.org/10.1055/s-2004-817752
Abstract
A highly regio- and chemoselective reductive cleavage of benzylidene acetals derived from 1,2- and 1,3-diols was achieved under mild conditions using EtAlCl2-Et3SiH reagent system in good to excellent yields. Labile protecting groups such as N-Boc, N-Cbz and -OTBDMS are found to be stable under the reaction conditions.
Item Type: | Article |
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Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
Keywords: | Regioselectivity; Chemoselectivity; Reductive Cleavage; Benzylidene Acetal; EtAlCl2; Et3SiH |
ID Code: | 98554 |
Deposited On: | 19 Sep 2014 11:49 |
Last Modified: | 19 Sep 2014 11:49 |
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