1,3:4,6-Di-O-benzylidene-d-mannitol as a source for novel chiral intermediates through regioselective reductive cleavage

Aravind, Appu ; Baskaran, Sundarababu (2005) 1,3:4,6-Di-O-benzylidene-d-mannitol as a source for novel chiral intermediates through regioselective reductive cleavage Tetrahedron Letters, 46 (5). pp. 743-745. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.12.036

Abstract

Synthetically useful chiral intermediates have been synthesized starting from 1,3:4,6-di-O-benzylidene-d-mannitol by regioselective reductive cleavage using BF3·Et2O and Et3SiH in high yields.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Regioselective; Reductive Cleavage; Chiral Intermediates; Chemoselective; Benzylidene Acetals
ID Code:98549
Deposited On:18 Sep 2014 11:11
Last Modified:18 Sep 2014 11:11

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