Photoinduced electron transfer from the inorganic core to the organic shell of hybrid core-shell nanoparticles: impedance spectroscopy

Guchhait, Asim ; Pal, Amlan J. (2012) Photoinduced electron transfer from the inorganic core to the organic shell of hybrid core-shell nanoparticles: impedance spectroscopy Chemistry - An Asian Journal, 7 (5). pp. 1096-1102. ISSN 1861-4728

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/asia.20...

Related URL: http://dx.doi.org/10.1002/asia.201101008

Abstract

In hybrid core–shell nanoparticles with inorganic nanocrystals in the core and organic molecules in the shell, photoinduced electron transfer occurs from the core to the shell. This leads to exciton dissociation through an ultrafast electron-transfer process that results in charge separation and finally photocurrent in the external circuit in devices based on such core–shell nanoparticles. In this work, we have fabricated and characterized sandwiched devices based on a series of core–shell systems. From impedance spectroscopy, we have observed that photoinduced charge separation in core–shell systems is associated with a decrease in the device resistance and an increase in the dielectric constant of the active material. In the series of core–shell systems, we have observed a one-to-one correlation between the photoinduced electron-transfer process and the changes in resistive and dielectric parameters upon illumination.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Electron Transfer; Impedance Spectroscopy; Nanoparticles; Organic–inorganic Hybrid Composites; Photovoltaic Devices
ID Code:98366
Deposited On:05 Jun 2014 05:21
Last Modified:05 Jun 2014 05:21

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