Mechanism of reduction of 3,4,5-triphenylfuran-2(5H)-ones by lithium aluminium hydride

Dikshit, Dinesh K. ; Munshi, Kishan L. ; Kapil, Randhir S. ; Anand, Nitya (1977) Mechanism of reduction of 3,4,5-triphenylfuran-2(5H)-ones by lithium aluminium hydride Journal of the Chemical Society, Perkin Transactions 1 (9). pp. 1087-1091. ISSN 0300-922X

Full text not available from this repository.

Official URL: http://pubs.rsc.org/en/content/articlelanding/1977...

Related URL: http://dx.doi.org/10.1039/P19770001087

Abstract

A detailed study of the reduction of 3,4,5-triphenylfuran-2(5H)-ones with lithium aluminium hydride, with deuterium as a marker, has been performed. On the basis of the results it is proposed that 1,4-hydride attack is followed by regiospecific hydridoalumination of the enolate double bond only in those cases where the resulting complex can be stabilised.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:96931
Deposited On:11 Feb 2013 06:51
Last Modified:11 Feb 2013 06:51

Repository Staff Only: item control page