Coarsening of second phase in a two-phase Zr-2.5Nb: on the role of phase boundaries

Abstract

Deformed two-phase Zr-2.5Nb was subjected to 700° C annealing and associated coarsening. After primary recrystallization, the second-phase body-centered cubic β was well dispersed on the grain boundaries of hexagonal β matrix. Prolonged annealing led to the presence of the β, mainly at the β tri-junctions. The two-phase coarsening was associated with clear trends of widening in the second-phase size distribution and changes in phase boundary nature. The former is contrary to what is expected. Changes in phase boundary nature were through increased concentration of 45°[001] phase boundaries-good-fit interfaces, present in larger β particles, which were estimated to have higher three-dimensional lattice coincidence and hence lower energy. Simple analytical modeling, assuming dissolution-controlled particle coarsening and a lower interfacial energy of the phase interface with the 45°[001], was shown to explain these experimental observations.