Ajayaghosh, Ayyappanpillai ; Varghese, Reji ; George, Subi Jacob ; Vijayakumar, Chakkooth (2006) Transcription and amplification of molecular chirality to oppositely biased supramolecular π helices Angewandte Chemie International Edition, 45 (7). pp. 1141-1144. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200503142
Abstract
Let's twist again: Transcription of molecular chirality from common stereogenic centers to amplified supramolecular chirality during the coassembly of gel-forming π-conjugated molecules by inverted helicity results in the formation of longitudinally fused M and P helices. This “sergeants and soldiers” approach to coassembly under stereomutation has been confirmed by CD and AFM techniques (see picture).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Chirality; Gels; Helical Structures; Scanning Probe Microscopy; Self-Assembly |
| ID Code: | 96149 |
| Deposited On: | 05 Dec 2012 11:59 |
| Last Modified: | 05 Dec 2012 11:59 |
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