Electron-phonon coupling and monopolar charge fluctuations in intermediate valence TmSe

Stüβer, N. ; Barth, M. ; Güntherodt, G. ; Jayaraman, A. (1981) Electron-phonon coupling and monopolar charge fluctuations in intermediate valence TmSe Solid State Communications, 39 (9). pp. 965-968. ISSN 0038-1098

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0038-1098(81)90066-1

Abstract

Polarized Raman spectra of intermediate valence TmxSe (x=0.95, 1.00, 1.01) have been measured. The scattering intensity is interpreted in terms of a one-phonon density of states weighted by the electron-phonon matrix element. The latter is described in a model of phonon-induced local, intraionic charge deformabilities. In the symmetry-analysed Raman intensities of A1g character, two peaks near 8.8meV and 21.9meV are attributed to monopolar charge deformations of the valence-fluctuating Tm ions.

Item Type:Article
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ID Code:96021
Deposited On:30 Nov 2012 07:06
Last Modified:30 Nov 2012 07:06

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