Gokhale, P. D. ; Joshi, A. P. ; Sahni, R. ; Naik, V. G. ; Damodaran, N. P. ; Nayak, U. R. ; Dev, S. (1976) Photochemical transformations—I Tetrahedron, 32 (12). pp. 1391-1393. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4020(76)85016-8
Abstract
Photo-irradiation of longibornyl iodide in n-heptane containing some triethylamine as scavenger for hydrogen iodide, furnished rearranged hydrocarbons (longifolene, longicyclene and longiborn-8-ene). Citronellyl iodide, under similar conditions, led to simple elimination (to furnish 2,6-dimethylocta-2,7-diene) and π-participation (to yield trans-p-menth-8-ene) to almost equal extent. A possible mechanism for these reactions is discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 95930 |
| Deposited On: | 05 Dec 2012 07:14 |
| Last Modified: | 18 Feb 2013 06:02 |
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