Cu 2p core-level photoemission spectrum of Sr2CuO3

Okada, Kozo ; Kotani, Akio ; Maiti, K. ; Sarma, D. D. (1996) Cu 2p core-level photoemission spectrum of Sr2CuO3 Journal of the Physical Society of Japan, 65 (6). pp. 1844-1848. ISSN 0031-9015

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Official URL: http://jpsj.ipap.jp/link?JPSJ/65/1844/

Related URL: http://dx.doi.org/10.1143/JPSJ.65.1844

Abstract

We measure the Cu 2p X-ray photoemission spectrum (XPS) of Sr2CuO3 and analyze it by means of exact diagonalization calculations for (CunO3n)4n- clusters. In Sr2CuO3, the intensity ratio of the 3d9 satellite to the 3d10 L main line is 0.35–0.4, which is evidently smaller than that in the other high-T c related cuprates. We ascribe it as the smaller charge-transfer energy between the Cu 3d and O 2p. The origin of the broad main-line of Sr2CuO3 is also discussed.

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