Manikandan, Palanichamy ; Varghese, Babu ; Manoharan, Periakaruppan T. (1996) Structure, characterisation and dynamics of copper(I) complexes of 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine Journal of the Chemical Society, Dalton Transactions (3). pp. 371-376. ISSN 1472-7773
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1996...
Related URL: http://dx.doi.org/10.1039/DT9960000371
Abstract
Two mononuclear copper(I) complexes of a tripodal ligand, 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine (L), have been prepared, [CuL(ClO4)]·CH2Cl21 and [CuL(PPh3)]ClO42. A new route to L is also proposed. The crystal structures of both complexes have been determined. In 1 the perchlorate is bonded through one of its oxygens with a distance of 2.426(3)Å. In 2 the perchlorate ion is thermally disordered. A variable-temperature NMR study of both complexes revealed that the methylene carbon of 2 is chiral at low temperatures. Carbon monoxide formed a terminal adduct with 1.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 95720 |
| Deposited On: | 11 Jan 2013 12:40 |
| Last Modified: | 11 Jan 2013 12:40 |
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