Structure of dichlorobis[P,P,P',P'-tetramethyl-o-phenylenebis(phosphine)]nickel(III) hexafluorophosphate dihydrate, [NiCl2{P2(CH3)4(C6H4)}2]PF6.2H2O

Mahadevan, C. ; Seshasayee, M. ; Ramakrishna, B. L. ; Manoharan, P. T. (1985) Structure of dichlorobis[P,P,P',P'-tetramethyl-o-phenylenebis(phosphine)]nickel(III) hexafluorophosphate dihydrate, [NiCl2{P2(CH3)4(C6H4)}2]PF6.2H2O Acta Crystallographica Section C, 41 (1). pp. 38-40. ISSN 0108-2701

Full text not available from this repository.

Official URL: http://scripts.iucr.org/cgi-bin/paper?S01082701850...

Related URL: http://dx.doi.org/10.1107/S0108270185002700

Abstract

Mr=706.9, monoclinic, C2/m, a=12.467(6), b=10.497), c=11.241(7)Å, β=100.79(4), V=1445 Å3, Z=2, Dx=1.625 Mg m-3, Mo Ka, λ=0.71069 Å, μ=1.108 mm-1, F(000)=726, room temperature, final R=0.087 for 1365 unique reflections. The Ni atom has a tetragonally distorted octahedral configuration with chlorine atoms in the axial positions and the anionic P atom has a regular are 2.424(4) and 2.255(3) Å. The anion and cation are held together by van der Waals forces.

Item Type:Article
Source:Copyright of this article belongs to International Union of Crystallography.
ID Code:95690
Deposited On:20 Nov 2012 10:57
Last Modified:20 Nov 2012 10:57

Repository Staff Only: item control page