Mahadevan, C. ; Seshasayee, M. ; Radha, A. ; Manoharan, P. T. (1984) Structure of bis(tetraethylammonium) bis[dimercaptomaleodinitrilato(2–)-S,S']nickelate(II), [N(C2H5)4]2[Ni(C4N2S2)2] Acta Crystallographica Section C Crystal Structure Communications, C40 (12). pp. 2032-2034. ISSN 0108-2701
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Official URL: http://scripts.iucr.org/cgi-bin/paper?a24057
Related URL: http://dx.doi.org/10.1107/S0108270184010519
Abstract
Mr=599.57, triclinic, P1, a=7.5608(7), b-8.7017(9), c=12.626(3)Å, a=93.73(1), β=104.27(1), y=75.257(9)°, V=779 Å3, Z=1, D=1.286, Dx =1.279g cm-3, λ(Mo Ka)=0.71069 Å, μ=8.54 cm-1, F(000)=318, T= 293 K. Final R=0.58 for 1550 unique observed diffractometer data. The metal atom of the anion has an approximately square-planar configuration and the amino atoms of the cations an approximately tetrahedral configuration. The Ni-S distances are 2.171(2) and 2.177(2) Å and the bite angle is 92.3(1)0. The anion is essentially planar with the Ni atom deviating most by 0.047(1)Å.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to International Union of Crystallography. |
| ID Code: | 95689 |
| Deposited On: | 20 Nov 2012 10:59 |
| Last Modified: | 20 Nov 2012 10:59 |
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