Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)2

Ramakrishna, B. L. ; Manoharan, P. T. (1983) Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)2 Chemical Physics Letters, 97 (1). pp. 98-102. ISSN 0009-2614

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0009-2614(83)87192-9

Abstract

The exchange coupling constant J in bis(diethyldithiocarbamato)copper(II) has been derived through analysis of the EPR g values and linewidth as a function of orientation, frequency and temperature. The single line in the ac* plane is due to the averaging of the fine-structure splitting by interdimer exchange for which a lower limit of 0.02 cm−1 has been obtained. Analysis of the spectra in the bc plane gives an estimate of 0.008 cm−1 for the intersite exchange.

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