A new decavanadate salt incorporating both inorganic and organic cations

Baruah, Bharat ; Chakravorty, Animesh (2002) A new decavanadate salt incorporating both inorganic and organic cations Indian Journal of Chemistry - Section A: Inorganic, Physical, Theoretical and Analytical Chemistry, 41A (12). pp. 2447-2449. ISSN 0376-4710

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Abstract

The title salt, [Cs2(H2O)2(tea)2H2V10O28] has been isolated by reacting a solution of V2O5 in aqueous H2O2 with [tea][Cl] and CsCl (tea+ is triethanolammonium cation). The structure of the salt consists of an unusual three-dimensional array of centrosymmetric H2V10O284- units (protonation sites consistent with bond valence sums) strongly interlinked by cesium ions which are chelated by the tea+ ligand.

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Deposited On:02 Nov 2012 07:16
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