Shivakumar, Maya ; Pramanik, Kausikisankar ; Ghosh, Prasanta ; Chakravorty, Animesh (1998) Synthesis and characterisation of a pair of azo anion radicals bonded to ruthenium(II) Chemical Communications (19). pp. 2103-2104. ISSN 1359-7345
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/1998...
Related URL: http://dx.doi.org/10.1039/A804480E
Abstract
The reactions of 1-methyl-2-(p-chlorophenylazo)imidazole (L1) and 2-(phenylazo)pyridine (L2) with [Ru(H)(X)- (CO)(PPh3)3] (X = Cl, Br) have afforded the green paramagnetic (S = ½) and EPR-active (g ≈ 2.00) title anion radical complexes [Ru(L1·–)(Cl)(CO)(PPh3)2] 1 and [Ru(L2·–)(Br)(CO)(PPh3)2] 2 in which the N–N bond lengths lie near 1.35 Å.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 95323 |
| Deposited On: | 31 Oct 2012 10:05 |
| Last Modified: | 31 Oct 2012 10:05 |
Repository Staff Only: item control page
