Chakravarty, Joydip ; Dutta, Somnath ; Chakravorty, Animesh (1993) A VO3+ complex incorporating aromatic carboxylate binding: synthesis, structure and metal redox Journal of the Chemical Society, Chemical Communications (13). pp. 1091-1092. ISSN 0022-4936
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1993...
Related URL: http://dx.doi.org/10.1039/C39930001091
Abstract
In the title complex [VOL1L2] derived from the tridentate 2-hydroxy-2′-carboxy-5-methylazobenzene (H2L1) and the bidentate quinolin-8-ol (HL2) the V–O(carboxylate) and V–N(azo) distances are respectively 1.892(4) and 2.098(5)Å; frozen solution (77 K) EPR parameters of electrogenerated [VOL1L2]– lie close to those of reduced bromoperoxidase (low pH).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Soceity of Chemistry. |
| ID Code: | 95308 |
| Deposited On: | 31 Oct 2012 12:07 |
| Last Modified: | 31 Oct 2012 12:07 |
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