Chemistry of ferroverdin: trinuclear species of type [M(FeL3)2](M = Mg, Ca, Mn, Fe, Co, Ni, Zn, or Cd; L = 4-methyl-1,2-benzoquinone 2-oximate)

Basu, Partha ; Pal, Samudranil ; Chakravorty, Animesh (1990) Chemistry of ferroverdin: trinuclear species of type [M(FeL3)2](M = Mg, Ca, Mn, Fe, Co, Ni, Zn, or Cd; L = 4-methyl-1,2-benzoquinone 2-oximate) Journal of the Chemical Society, Dalton Transactions (1). pp. 9-11. ISSN 1472-7773

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1990...

Related URL: http://dx.doi.org/10.1039/DT9900000009

Abstract

Reaction of sodium tris (4-methyl-1,2-benzoquinone 2-oximato) ferrate(II), Na[FeL3], with M2+(M = Mg, Ca, Mn, Fe, Co, Ni, Zn, or Cd) in methanol furnishes trinuclear species of type [M(FeL3)2]. Upon treatment with NaOH, M(OH)2 is precipitated and Na[FeL3] is regenerated. The iron(II) atoms of the two [FeL3] moieties in the trinuclear complexes are low spin but M2+ is high spin (S=5//2, 2, 3/2, and 1 in the cases of M = Mn, Fe, Co, and Ni respectively). The M2+ site can be doped with Mn2+ and e.s.r. data for the doped complexes are compatible with a near octahedral environment of the M2+ site. It is proposed that this environment is created by the six oximato oxygen atoms of the two facial [FeL3] moieties. The significance of the present work in relation to the reported variation of the iron content in different preparations of ferroverdin is noted.

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