Basu, Partha ; Pal, Samudranil ; Chakravorty, Animesh (1989) Redox in a ferroverdin analogue: recognition of isomeric co-ordination spheres by FeII and FeIII Journal of the Chemical Society, Chemical Communications, 15 . pp. 977-978. ISSN 0022-4936
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/1989...
Related URL: http://dx.doi.org/10.1039/C39890000977
Abstract
The N3O3 co-ordination sphere of (1b) and (1c) selectively stabilises low-spin FeII and FeIII in fac(2a) and mer(2b) geometries, respectively; mismatched combinations generated by rapid chemical/electrochemical electron transfer at low temperatures undergo spontaneous isomerisation at measurable rates to achieve equilibrium populations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Soceity of Chemistry. |
| ID Code: | 95292 |
| Deposited On: | 30 Oct 2012 09:29 |
| Last Modified: | 30 Oct 2012 09:29 |
Repository Staff Only: item control page
