Goswami, Sreebrata ; Chakravarty, Akhil R. ; Chakravorty, Animesh (1982) The RuII(OH2)–RuIV(O) couple in a ruthenium complex of 2-(phenylazo)pyridine : homogeneous catalysis of the oxidation of water to dioxygen Journal of the Chemical Society, Chemical Communications (22). pp. 1288-1289. ISSN 0022-4936
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1982...
Related URL: http://dx.doi.org/10.1039/C39820001288
Abstract
In acidic solution [RuII(OH2)(py)L2]2+ can be oxidised to [RuIV(O)(py) L2]2+ in a single reversible step (E°298= 1.20V) and the oxidised complex catalyses the dehydorgenation of water to dioxygen in the presence of Ce4+[py = pyridine; L = 2-(phenylazo)pyridine].
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Soceity of Chemistry. |
| ID Code: | 95284 |
| Deposited On: | 30 Oct 2012 05:33 |
| Last Modified: | 30 Oct 2012 05:33 |
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