Behera, B. ; Chakravorty, A. (1969) Studies on some new neutral tris-complexes of trivalent rhodium and chromium Journal of Inorganic and Nuclear Chemistry, 31 (6). pp. 1791-1796. ISSN 0022-1902
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-1902(69)80397-0
Abstract
Synthesis of tris-chelates of Rh(III) and Cr(III) derived from several triazene-1-oxides is described. The electronic spectra of the complexes are discussed. A typical Cr(III)-complex is characterised by the crystal field parameters: Dq = 1740 cm−1 and B = 508 cm−1. Proton resonance data unequivocally established the trans stereochemistry for the Rh(III) complexes. The sterically unfavorable cis form could not be synthesised.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 95237 |
| Deposited On: | 25 Oct 2012 05:03 |
| Last Modified: | 25 Oct 2012 05:03 |
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