Wakeshima, M. ; Sato, N. ; Fujino, T. ; Waseda, Y. ; Matsubara, E. ; Jacob, K. T. ; Saito, M. (1995) The structure of amorphous platinum disulfide as studied by anomalous X-ray scattering ChemInform, 26 (12). ISSN 0931-7597
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chin.19...
Related URL: http://dx.doi.org/10.1002/chin.199512001
Abstract
Anomalous X-ray scattering (AXS) has been applied to study the structure of amorphous platinum disulfide, Pt1-xS2, prepared by the precipitation process. The local atomic arrangement in amorphous Pt1-xS2 was determined by the least-squares variational method so as to reproduce the experimental differential interference function at the Pt L(III) absorption edge by the AXS method as well as the ordinary interference function by MoK alpha. The structural unit in amorphous Pt1-xS2 is found to be a PtS6 octahedron, similar to that in crystalline PtS2. These octahedra share both their corners and edges, while only edge-sharing linkages occur in crystalline PtS2.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Structure (Solids and Liquids); Platinum, Pt; Sulfur, S |
| ID Code: | 94936 |
| Deposited On: | 11 Oct 2012 11:42 |
| Last Modified: | 11 Oct 2012 11:42 |
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