Srikanth, S. ; Jacob, K. T. (1989) Extension of Darken's quadratic formalism to dilute multicomponent solutions ISIJ International, 29 (2). 171-174 . ISSN 0915-1559
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Official URL: https://www.jstage.jst.go.jp/article/isijinternati...
Related URL: http://dx.doi.org/10.2355/isijinternational.29.171
Abstract
Darken's quadratic formalism is extended to multicomponent solutions. Equations are developed for the representation of the integral and partial excess free energies, entropies and enthalpies in dilute multicomponent solutions. Quadratic formalism applied to multicomponent solutions is thermodynamically consistent. The formalism is compared with the conventional second order Maclaurin series or interaction parameter representation and the relations between them are derived. Advantages of the quadratic formalism are discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Japan Science and Technology Information Aggregator, Electronic. |
| Keywords: | Quadratic Formalism; Interactin Parameters; Enthalpy and Entropy Parameters; Thermodynamic Consistency |
| ID Code: | 94852 |
| Deposited On: | 05 Oct 2012 09:30 |
| Last Modified: | 05 Oct 2012 09:30 |
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