Assessing surface permeabilities from transient guest profiles in nanoporous host materials

Tzoulaki, Despina ; Heinke, Lars ; Lim, Hyuna ; Li, Jing ; Olson, David ; Caro, Jürgen ; Krishna, Rajamani ; Chmelik, Christian ; Karger, Jörg (2009) Assessing surface permeabilities from transient guest profiles in nanoporous host materials Angewandte Chemie International Edition, 48 (19). pp. 3525-3528. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...

Related URL: http://dx.doi.org/10.1002/anie.200804785

Abstract

Easy come, easy go? Transport resistances on particle surfaces are important for mass transfer in nanoporous materials and bulk diffusion in crystals. Interference microscopy and IR micro-imaging are shown to be excellent tools for determining such transport resistances. By studying short-chain-length alkane guest molecules in crystals of the metal-organic framework compound Zn(tbip) a data collection of surface permeabilities is established.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Coordination Polymers; Nanoporous Materials; Surface Permeability; Surface Resistance
ID Code:93765
Deposited On:25 Jun 2012 13:11
Last Modified:25 Jun 2012 13:11

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