Nagarajan, K. ; Ranga Rao, V. ; Venkateswarlu, A. (1970) Synthesis of some pyrimido[1,6-a]benzimidazole derivatives Indian Journal of Chemistry, 8 . pp. 126-129. ISSN 0019-5103
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Abstract
The base-catalysed condensation of 2-(p-'amihoethyl)benzimidazole (V) with a variety of aldehydes,such as formaldehyde, benzaldehyde, p-chlorobenzaldehyde,etc, yields tetrahydropyrimido-[1,6-a], benzimidazoles (VI). The NMR spectral data of the products decidedly favour a cyclic structure VI as compared to the isomeric open chain Schiff's base (VII). Condensation of carbon disulphide with V affords 3,4-dihydropyrimido[l,6-a]benzimidazole-l(2H)thione (XV). With piperidine and morpholirie, XV yields the thiocarbamoyl derivatives (XVI) of the original amine (V).
Item Type: | Article |
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Source: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
ID Code: | 93450 |
Deposited On: | 16 Jun 2012 09:13 |
Last Modified: | 19 May 2016 06:32 |
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