Formation of protoberberines by debenzylation and photolysis of tetrahydroisoquinolines

Pai, Bantwal R. ; Nagarajan, Kuppuswamy ; Premila, Manakkal S. ; Suguna, Hosbett (1975) Formation of protoberberines by debenzylation and photolysis of tetrahydroisoquinolines Heterocycles, 3 (10). pp. 811-812. ISSN 0385-5414

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Official URL: http://www.heterocycles.jp/newlibrary/libraries/ab...

Related URL: http://dx.doi.org/10.3987/R-1975-10-0811

Abstract

Treatment of 1-(3-benzyloxybenzyl)-1,2,3,4-tetra-hydroisoquinolines (1, 5 and 6) with hydrochloric acid in ethanol without formalin gave the corresponding phenolic isoquinolines (2, 8 and 9) and the tetrahydro-prbtoberberines (3, 11 and 12). The former products (2, 8 and 9) on photolysis also gave the tetrahydroproto-berberines (3, 11 and 12) together with the normal products, aporphines.

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ID Code:93436
Deposited On:16 Jun 2012 09:20
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