Mahata, P. K. ; Barun, O. ; Ila, H. ; Junjappa, H. (2000) Formation of acetaldehyde enolate from vinyl acetate and its reaction with aromatic and heteroaromatic aldehydes: an efficient synthesis of enals and polyenals Synlett (9). pp. 1345-1347. ISSN 0936-5214
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Official URL: https://www.thieme-connect.de/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2000-7142
Abstract
Two carbon homologation of aromatic and heterocyclic aldehydes is achieved by reacting them with acetaldehyde enolate anion generated in situ by cleaving vinyl acetate in the presence of barium hydroxide. cross aldol condensation - two carbon homologation - dienals - bismethylthioacrolein - ethyl 3,3-bis(methylthio)-2-propenoate.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| ID Code: | 92887 |
| Deposited On: | 08 Jun 2012 09:01 |
| Last Modified: | 11 Jul 2012 04:30 |
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