A novel chiral auxiliary for enantioselective synthesis of tertiary alcohol

Ranu, Brindaban C. ; Chakraborty, Rupak ; Sarkar, Dipak C. (1991) A novel chiral auxiliary for enantioselective synthesis of tertiary alcohol Synthetic Communications, 21 (15-16). pp. 1619-1624. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397919108021061

Abstract

The use of 1-menthyl ester of 1,3-dithiane-2-carboxylic acid as a chiral auxilary for the conversion of acetophenone, propiophenone and butyrophenone to the corresponding optically active tertiary alcohols 2-phenylhexan-2-ol, 3-phenylheptan-3-ol and 4-phenyloctan-4-ol, has been demonstrated.

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