Ruthenium(III)-catalysed phenylselenylation of allyl acetates by diphenyl diselenide and indium(I) bromide in neat: isolation and identification of intermediate

Saha, Amit ; Ranu, Brindaban C. (2011) Ruthenium(III)-catalysed phenylselenylation of allyl acetates by diphenyl diselenide and indium(I) bromide in neat: isolation and identification of intermediate Organic and Biomolecular Chemistry, 2011 (6). pp. 1763-1767. ISSN 1477-0520

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2011...

Related URL: http://dx.doi.org/10.1039/C0OB00317D

Abstract

A fast and efficient phenylselenylation of allyl acetates by diphenyl diselenide and indium(I) bromide has been achieved in neat under the catalysis of Ru(acac)3. The intermediate complex of diphenyl diselenide and indium has been isolated and identified as a polymeric pentacoordinated In(III) selenolate complex, [In(SePh)3]n.

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Deposited On:05 Jun 2012 10:27
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