Ahammed, Sabir ; Saha, Amit ; Ranu, Brindaban C. (2011) Hydrogenation of azides over copper nanoparticle surface using ammonium formate in water Journal of Organic Chemistry, 76 (17). pp. 7235-7239. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo200915h
Related URL: http://dx.doi.org/10.1021/jo200915h
Abstract
Aryl azides undergo clean reduction by copper nanoparticles and ammonium formate in water. The surface hydrogen on copper nanoparticles is considered to be the active reducing species. A variety of functionalized aryl azides and aryl sulfonyl azides are reduced by this procedure to the corresponding amines with excellent chemoselectivity in high yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 92833 |
| Deposited On: | 05 Jun 2012 10:27 |
| Last Modified: | 05 Jun 2012 10:27 |
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