Devanathan, S. ; Ramamurthy, V. (1987) Consequences of hydrophobic association in photoreactions: photodimerization of alkyl cinnamates in water Journal of Photochemistry, 40 (1). pp. 67-77. ISSN 0047-2670
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0047-2670(87)87045-4
Abstract
Photolysis of alkyl cinnamates in water gave d-truxinates in near quantitative yields. Dimerization of alkyl cinnamates at low concentration (about 10-4 M) in water is attributed to hydrophobic association of these solutes. At such low concentrations, photolysis in benzene and methanol yields only geometric isomers. This study illustrates the potential of water as a solvent for photoreactions and stresses the need for increased appreciation of its utility.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 91442 |
| Deposited On: | 21 May 2012 12:10 |
| Last Modified: | 21 May 2012 12:10 |
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