Phonon-assisted asymmetric tunneling in a double-well potential: consequences for neutron scattering and diffusion

Dattagupta, S. ; Schober, H. R. (1998) Phonon-assisted asymmetric tunneling in a double-well potential: consequences for neutron scattering and diffusion Physical Review B: Condensed Matter and Materials Physics, 57 (13). pp. 7606-7614. ISSN 1098-0121

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Official URL: http://prb.aps.org/abstract/PRB/v57/i13/p7606_1

Related URL: http://dx.doi.org/10.1103/PhysRevB.57.7606

Abstract

We investigate the dynamics of a light interstitial atom in a double-well potential and extend the small polaron theory to include tunneling transitions from the ground state to excited states as well as asymmetry between sites. Starting from a generalized spin-boson Hamiltonian we use the resolvent of the time-development operator to derive formulas for transition rates and neutron-scattering structure factors. We show how with only two parameters the model allows for a quantitative description of hydrogen diffusion in bcc metals up to high temperatures. Asymmetry between the wells strongly reduces the mobility, particularly at low temperatures.

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Source:Copyright of this article belongs to American Physical Society.
ID Code:9134
Deposited On:29 Oct 2010 11:33
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