Elastic properties of lead phosphomolybdate glasses

Damodaran, K. V. ; Selvaraj, U. ; Rao, K. J. (1988) Elastic properties of lead phosphomolybdate glasses Materials Research Bulletin, 23 (8). pp. 1151-1158. ISSN 0025-5408

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0025-5408(88)90205-X

Abstract

Elastic properties of lead phosphomolybdate [PbO-1bMoO3-1bP2O5] glasses have been investigated using ultrasonic velocity measurements at 10MHz. The composition dependence of elastic moduli, Poisson's ratio and the Debye temperature are found to be consistent with a structural model proposed earlier. According to this model lead acts both as a network former and as a network modifier in different composition regimes. It is suggested that the incorporation of lead into the network is accompanied by the conversion of three-connected [POO3/2] tetrahedra into four-connected [PO4/2]+ tetrahedra in the network.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Lead; Phosphorus; Molybdenum
ID Code:91193
Deposited On:17 May 2012 04:13
Last Modified:17 May 2012 04:13

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