31P MAS NMR investigations of crystalline and glassy NASICON-type phosphates

Sobha, K. C. ; Rao, K. J. (1996) 31P MAS NMR investigations of crystalline and glassy NASICON-type phosphates Journal of Solid State Chemistry, 121 (1). pp. 197-201. ISSN 0022-4596

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1006/jssc.1996.0028

Abstract

31P MAS NMR investigations of crystalline and glassy NASICON-type phosphates have been carried out. The origin for the two signals in the case of the crystalline compounds is discussed. The spectra show the presence of pyrophosphate units in all glasses studied along with various other phosphate species resulting from structural disproportionation.

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