Synthesis of racemic and optically active forms of 16α-strychindols; chemical derivative of the absolute configuration of strychnine. 56th Notice of curare alkaloids

Nagarajan, K. ; Weissmann, Ch. ; Schmid, H. ; Karrer, P. (1963) Synthesis of racemic and optically active forms of 16α-strychindols; chemical derivative of the absolute configuration of strychnine. 56th Notice of curare alkaloids Helvetica Chimica Acta, 46 (4). pp. 1212-1231. ISSN 0018-019X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/hlca.19...

Related URL: http://dx.doi.org/10.1002/hlca.19630460417

Abstract

In previous releases of the degradation of strychnine on 19,20-dihydro-strychnine (11) was added to 3-hydroxy-l6β strychindol described (VI) was now in (-) -16α Strychindol-((-)-VII) is converted, which of the seven asymmetric centers in their nurmehr II contains three with known relative configuration.

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