Chandrasekhar, Vadapalli ; Nehete, Umesh N. ; Roesky, Herbert W. ; Magull, Jorg (2004) the formal conversion of SiOH protons into hydrides by germanium(II) species leads to the formation of the germanium(IV) hydride cluster [(RSiO3GeH)4] Angewandte Chemie International Edition, 44 (2). pp. 281-284. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200460849
Abstract
Germanium cubed: Addition of [Ge{N(SiMe3)2}2] to a suspension of RSi(OH)3 (R=(2,6-iPr2C6H3)N(SiMe3)) in hexane/THF affords the germanium siloxane 1 with terminal Ge-H units in good yield. Compound 1 contains a Ge4O12Si4 cubic polyhedron core in which the corners of the cube are alternately occupied by germanium and silicon atoms. Each of the twelve edges of the cube contains one bridging oxygen atom.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Cluster Compounds; Germanium; Hydrides; Oxidative Addition; Silicon |
| ID Code: | 9016 |
| Deposited On: | 29 Oct 2010 11:59 |
| Last Modified: | 29 Oct 2010 11:59 |
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