Shailaja, J. ; Sivaguru, J. ; Uppili, Sundararajan ; Joy, Abraham ; Ramamurthy, V. (2001) Use of a confined space (zeolite) in enantio-and diastereo-selective photoreactions Microporous and Mesoporous Materials, 48 (1-3). pp. 319-328. ISSN 1387-1811
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S1387-1811(01)00348-1
Abstract
The confined spaces of zeolites have been found to be ideal for carrying out enantio- and diastereo-selective photoreactions. Four methods, (chiral inductor, chiral auxiliary, a combination (chiral inductor + chiral auxiliary) and chiral inductor as a reagent) have been explored and all were found to give reasonable chiral induction on several systems. The uniqueness of zeolites as media although established in this study, the factors that control the high chiral induction in zeolite with respect to solution are yet to be established.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Zeolite; Enantioselectivity; Photoreactions; Chiral induction |
| ID Code: | 90061 |
| Deposited On: | 04 May 2012 14:32 |
| Last Modified: | 04 May 2012 14:32 |
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