Chandrasekhar, Vadapalli ; Boomishankar, Ramamoorthy ; Gopal, Kandasamy ; Sasikumar, Palani ; Singh, Puja ; Steiner, Alexander ; Zacchini, Stefano (2006) Synthesis, structure and reactivity of hydrated and dehydrated organotin cations European Journal of Inorganic Chemistry, 2006 (20). pp. 4129-4136. ISSN 1434-1948
Full text not available from this repository.
Official URL: http://www3.interscience.wiley.com/journal/1127505...
Related URL: http://dx.doi.org/10.1002/ejic.200600468
Abstract
Monomeric organotin dications {[nBu2Sn(H2O)4]2+·2C6H5SO3-} and {[nBu2Sn(H2O)4]2+·1,5-C10H6(SO3-)2} have been synthesized by the reaction of [nBu2SnO]n and the corresponding arylsulfonic acid. Dodecanuclear organooxotin macrocations {[(nBuSn)12(μ 3-O)14(μ 2-OH)6]2+·2RSO3-} (R = C6H5; 2,5-Me2C6H3) have been synthesized by the reaction of nBuSn(O)(OH) and the corresponding arylsulfonic acid. The X-ray crystal structure of one of the dodecanuclear cages is reported. These organotin cations have been shown to be effective catalysts in acetylation and transacetylation reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Organotin Cations; Organooxotin; Organostannoxane; Acetylation; Transacetylation |
| ID Code: | 8993 |
| Deposited On: | 29 Oct 2010 12:04 |
| Last Modified: | 29 Oct 2010 12:04 |
Repository Staff Only: item control page
