Chandrasekhar, Vadapalli ; Singh, Sanjay ; Kumar, S. Shravan ; Ahn, Hans-Jurgen ; Biadene, Marianna ; Roesky, Herbert W. ; Hosmane, Narayan S. ; Noltemeyer, Mathias ; Schmidt, Hans-Georg (2004) Tetranuclear homo-and heteroalumoxanes containing reactive functional groups: syntheses and X-ray crystal structures of [{[LAl(Me)](μ-O)(MH2)}2]] Angewandte Chemie International Edition, 43 (37). pp. 4940-4943. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200460395
Abstract
A core with corners: The first alumoxane containing an {Al4O2} core as well as a gallium congener with an {Al2Ga2O2} core are prepared by the reaction of an organoaluminum monohydroxide with MH3NMe3 (see formula; M=Al, Ga; Ar=2,6-iPr2C6H3). These compounds contain reactive hydride groups on the central M2O2 rings and methyl groups on the terminal aluminum atoms.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Aluminum; Alumoxanes; Gallium; Hydrides; Hydroxides |
| ID Code: | 8991 |
| Deposited On: | 29 Oct 2010 12:04 |
| Last Modified: | 29 Oct 2010 12:04 |
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