Chandrasekhar, Vadapalli ; Nehete, Umesh N. ; Anantharaman, Ganapathi ; Roesky, Herbert W. ; Vidovic, Denis ; Magull, Jorg (2004) Molecular {(SnO)6} trapped by two {R2Si2O3} fragments: X-ray single-crystal structure of [(SnO)6 (R2Si2O3)2] Angewandte Chemie International Edition, 43 (29). pp. 3842-3844. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/ange.200454149
Abstract
The hexatin(II) cage containing siloxane ligands is obtained by the addition of Sn[N(SiMe3)2]2 to a suspension of RSi(OH)3 in a hexane/THF mixture. The X-ray crystal structure analysis of compound 1 reveals a central {(SnO)6} motif enclosed by two outer {R2Si2O3} siloxane ligands.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Cluster Compounds; O Ligands; Silanes; Structure Elucidation; Tin |
| ID Code: | 8974 |
| Deposited On: | 29 Oct 2010 12:06 |
| Last Modified: | 29 Oct 2010 12:06 |
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