Chandrasekhar, Vadapalli ; Nagendran, Selvarajan ; Bansal, Sachin ; Kozee, Michael A. ; Powell, Douglas R. (2000) An iron wheel on a tin drum: a novel assembly of a hexaferrocene unit on a tin-oxygen cluster Angewandte Chemie International Edition, 39 (10). pp. 1833-1835. ISSN 1433-7851
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Official URL: http://www3.interscience.wiley.com/journal/7250187...
Related URL: http://dx.doi.org/10.1002/(SICI)1521-3773(20000515)39
Abstract
Based on reactions known in organotin chemistry, the robust hexaferrocene assembly [{BuSn(O)OC(O)Fc}6] is obtained in quantitative yield by the reaction of two commercially available reactants. The X-ray crystal structure shows a symmetric giant wheel arrangement of the ferrocene units attached in a cyclic manner to a central drumlike stannoxane core. Cyclic voltammetric studies show a single quasireversible oxidation peak.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Cluster Compounds; Cyclic Voltammetry; Iron; Metallocenes; Tin |
| ID Code: | 8972 |
| Deposited On: | 29 Oct 2010 12:06 |
| Last Modified: | 29 Oct 2010 12:06 |
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