Organostannoxane-supported palladium nanoparticles. Highly efficient catalysts for Suzuki-coupling reactions

Chandrasekhar, Vadapalli ; Narayanan, Ramakirushnan Suriya ; Thilagar, Pakkirisamy (2009) Organostannoxane-supported palladium nanoparticles. Highly efficient catalysts for Suzuki-coupling reactions Organometallics, 28 (20). pp. 5883-5888. ISSN 0276-7333

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Official URL: http://pubs.acs.org/doi/abs/10.1021/om900487h

Related URL: http://dx.doi.org/10.1021/om900487h

Abstract

A phosphine-rich hexameric organostannoxanne, [n-BuSn(O)COOL]6 (PDrum; L = p-PPh2-C6H4-), has been synthesized by a 6:6 reaction between [n-BuSn(O)OH]n and p-Ph2PC6H4COOH. 119Sn{1H} NMR of PDrum revealed a single resonance at -481.0 ppm, indicating that it possesses the characteristic drum structure that is well-known among organostannoxanes. Reduction of PdCl2 with NaBH4 in the presence of PDrum afforded a palladium nanocomposite, NP-1. HRTEM of NP-1 indicates that the average nanoparticle size is about 3 nm. The latter has been shown to be very effective in mediating Suzuki-coupling reactions involving a number of different substrates. NP-1 can be recycled, and HRTEM analysis of the used catalyst reveals some agglomeration. Treatment of NP-1 with n-hexane and cooling to -25 ° C afforded another palladium nanocomposite, NP-2. The latter also is very effective in catalyzing the Suzuki-coupling reaction. HRTEM of NP-2 shows an average nanoparticle size of about 4.3 nm, which remains nearly unchanged even after catalysis. NP-2 is a composite also containing some amounts of SnO2.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:8938
Deposited On:28 Oct 2010 10:31
Last Modified:28 Oct 2010 10:31

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