Chandrasekhar, Vadapalli ; Baskar, Viswanathan ; Boomishankar, Ramamoorthy ; Gopal, Kandasamy ; Zacchini, Stefano ; Bickley, Jamie F. ; Steiner, Alexander (2003) Solventless reactions for the synthesis of organotin clusters and cages Organometallics, 22 (18). pp. 3710-3716. ISSN 0276-7333
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Official URL: http://pubs.acs.org/doi/abs/10.1021/om030338c
Related URL: http://dx.doi.org/10.1021/om030338c
Abstract
Organotin clusters and cages have been synthesized in quantitative yields by using a benign solventless synthetic methodology. Using this method a variety of structural forms, which include the drum, O-capped cluster, tetranuclear oxo cage, discrete, and polymeric compounds, have been synthesized. All these compounds (1-11) have been characterized by spectroscopic and analytical techniques. The new compounds, which include the hexameric drum [n-BuSn(O)OCOAd]6 (Ad = adamantyl) 9, a triorganotin-based discrete structure Ph3SnO2C-C6H2-2,4,6-Me3 (10), and a polymer Ph3SnOSO2-C6H3-2,5-Me2 (11), have been characterized by single-crystal X-ray crystallography.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 8924 |
| Deposited On: | 28 Oct 2010 10:33 |
| Last Modified: | 28 Oct 2010 10:33 |
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