Wave packet dynamics of the HgI2 photodissociation reaction in solution

Pugliano, N. ; Palit, D. K. ; Szarka, A. Z. ; Hochstrasser, R. M. (1993) Wave packet dynamics of the HgI2 photodissociation reaction in solution The Journal of Chemical Physics, 99 (9). 7273_1-7273_4. ISSN 0021-9606

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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v99/i9/p7273_...

Related URL: http://dx.doi.org/10.1063/1.465422

Abstract

Using femtosecond absorption spectroscopy, the photodissociation dynamics of HgI2 in solution were investigated. Upon photolysis, the HgI fragment is formed in a coherent superposition of its vibrational states. Solvent dependence of the wave packet motion is evidenced by the different results for ethanol and DMSO and between solution and gas phase.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
Keywords:Wave Packets; Mercury Iodides; Photodissociation; Solutions; FS Range; Absorption Spectra; Photolysis; Vvibrational States; Solvents; Ethanol; DMSO; Gas Phase
ID Code:89179
Deposited On:30 Mar 2012 10:05
Last Modified:30 Mar 2012 10:05

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